The Air We Breathe

The United Nations Environment Program and World Health Organization now regard air pollution as the single largest threat to human health and the environment.

92%

of the world’s population breathe air above the WHO annual guideline

1 in 8

deaths worldwide is linked to pollution in the air

The real threat of air pollution

The smog hanging over cities like Los Angeles or Beijing is the most familiar and obvious form of air pollution. The United Nations Environment Program (UNEP) and World Health Organization (WHO) now regard air pollution as the single largest threat to human health and the environment.

There are many kinds of air pollution. Some pollution is visible to the naked eye. Most air pollution is not. Nearly all pollution is created by human activity. So what is it?

Scientists classify air pollution into two main categories:

Category one

Gases

CO2, sulfur dioxide, nitrogen oxides, methane

Category two

Suspended particles

Also known as particulate matter — microscopic liquid and solid particles

The mixture

Smog

Smog is the mixture of these two categories of pollutants.

WHO reports that over 92% of the world’s population are exposed to air pollution that is above the organization’s air quality guideline (AQG) annual mean levels of 10 μg/m3.

In terms of gases, carbon dioxide (CO2) is the main greenhouse pollutant that scientists and forward-looking governments are most concerned about. While all living things emit carbon dioxide, the bulk of CO2 emissions come from burning fossil fuels to power our cars, homes and factories. Since the industrial revolution, humans have raised the CO2 concentration higher than it has been for hundreds of thousands of years. The burning of fossil fuel for power and industrial factories produce other gaseous pollutants like sulfur dioxide, nitrogen oxides and methane, as well as particulate matter.

With respect to particulate matter (PM) pollution, these aerosols are microscopic liquid and solid particles suspended in the air.

From fuel to pollutant to effect
Source Fossil fuel power plants, industry, motor vehicles
Emitted CO2, SO2, NOX, methane, VOCs, particulate matter
Formed in air Ozone and secondary PM, when VOCs react with SOX and NOX
Effect Asthma, COPD, heart disease, stroke, cancer, acid rain, haze

Want to know more about air quality standards?

The US EPA monitors six criteria pollutants for the outdoors: lead (Pb), carbon monoxide (CO), sulfur dioxide (SO2), nitrogen dioxide (NO2), ozone (O3), and particulate matter (PM). These are part of the National Ambient Air Quality Standards (NAAQS). For a detailed look at the chemistry underlying these pollutants and their effects, see this page.

PM

Particulate matter

O3

Ozone

CO

Carbon monoxide

NO2

Nitrogen dioxide

SO2

Sulfur dioxide

Pb

Lead

What are the sources of PM?

PM pollution is emitted directly from fossil fuel power plants, industrial sources, and automobile emissions. Like ozone, PM is also formed from the reaction of VOCs with SOX and NOX gases. 2.7 million tons of PM pollution are released in the US each year.

2.7M

tons of PM released in the US each year

Pie chart of US particulate matter sources: industrial 48%, power generation 35%, highway vehicles 11%, non-road vehicles 7%
Sources of particulate matter pollution: industrial sources account for 48%, power generation 35%, highway vehicles 11% and non-road vehicles 7%.

Why does the particle size matter?

Drawn to scale · diameter in micrometers
100
Human hair 100 µm wide
PM10 10 µm or less
PM2.5 2.5 µm or less
PM10 particles do not remain airborne and tend to fall to the ground.
PM2.5 can remain airborne for long periods and migrate thousands of miles.

Particulate matter behaves differently depending on its size. They are classified as:

– PM10; 10 micrometers or less in diameter,

– PM2.5: 2.5 micrometers or less in diameter.

For reference, the width of a human hair is 100 micrometers. The larger PM10 particles do not remain airborne and tend to fall to the ground. Fine particulates, also known as PM2.5 can remain airborne for long periods and migrate thousands of miles.

What are the health effects of PM and ozone?

24M

people in the US have asthma

6M

of them are children, at least

$56B

estimated economic cost of asthma

There is overwhelming evidence of the health risks associated with exposure to inhaling PM2.5 and ozone. Those with heart or lung disease, the elderly, and children are at greater risk.

When inhaled, the particulates can penetrate the lower airways and some may even enter the bloodstream. Multiple studies show higher incidences of asthma, pneumonia, chronic obstructive pulmonary disease (COPD), heart disease, and stroke due to exposure. Today 24 million people in the US, including at least 6 million children have asthma. The economic cost of asthma is estimated to be at least $56 billion.

Diagram of three routes by which inhaled particles reach the brain: olfactory bulb transmission, nasal epithelial transmission and mechanical inhalation into the lungs releasing cytokines, with a size comparison of PM10 and PM2.5 against a 60 micrometer human hair
How inhaled particulates reach the body and the brain: through the olfactory bulb, the nasal epithelium, and the lungs.

PM is also a known carcinogen. Recent research suggests particulates harm the brain. The effects include accelerated cognitive aging, and may contribute to higher likelihood of Alzheimer’s and other forms of dementia.

What are the average levels for PM?

WHO guideline against observed urban range · μg/m3
PM2.5 urban average ranges from under 10 to over 100
0 100+ 10
WHO annual guideline
PM10 urban average ranges from 10 to over 200
0 200+ 20 70
WHO annual guideline Many developing countries average this
PM2.5 · annual mean 10 μg/m3
PM2.5 · 24 hours 25 μg/m3
PM10 · annual mean 20 μg/m3
PM10 · 24 hours 50 μg/m3

The WHO recommends exposure of PM2.5 to be limited to 10 μg/m3 annual mean and 25 μg/m3 for any 24-hour period. For PM10, the exposure should be limited to 20 μg/m3 annual mean and 50 μg/m3 for any 24-hour period.

World map plotting annual mean PM2.5 concentration in nearly 3,000 urban areas from 2008 to 2015, with the highest values across the Middle East, South Asia and China
Annual mean PM2.5 concentration in nearly 3,000 urban areas, 2008–2015. Source: World Health Organization, © WHO 2016.

The concentration of PM depends on a number of factors such as proximity to power plants and highways. In urban areas, the average concentration of PM2.5 ranges from less than 10 to over 100 μg/m3 depending on the location and prevailing winds. For PM10, from 10 to over 200 μg/m3. In many developing countries the concentration of PM10 averages 70 μg/m3, far exceeding WHO guidelines.

Is the mix of air pollution the same around the world?

Eastern Europe

More sulfur dioxide and nitrogen oxides

More coal plants burning lignite coal. SO2 is also the source of acid rain.

San Francisco Bay Area

Less sulfur, more particulate matter

Fewer coal-fired power plants, but a large number of cars and major roadways.

Air pollution is not the same in different parts of the world. In Eastern Europe, where there are more coal plants burning lignite coal, we see more sulfur dioxide (also the source of acid rain) and nitrogen oxides. In the San Francisco Bay Area, there are fewer power plants that use coal so we see less sulfur but more particulate matter due to the number of cars and major roadways.

Topography, along with urban and building design, play critical roles in the dispersion and accumulation of air pollutants. A recent study in Central North Carolina suggests that previous studies may have underestimated premature death for individuals living within 1000 meters of a roadway.

Is there such a thing as air pollution at home?

Consumer products and building materials emit volatile organic compounds (VOCs). These are released from carpet, plywood, paint solvents, air fresheners, scented candles, glues, cleaners, etc. A common source of VOCs in the home is dry cleaned clothes. Your clothes may be washed in perchloroethylene or tetrachloroethylene.

Without adequate ventilation, VOCs and particulates concentrate in buildings, causing a wide range of health conditions known as “sick building syndrome” (SBS). Some VOCs cause eye irritation or breathing difficulty while others are known carcinogens and can trigger the formation of smog. Here is a link that summarizes household air pollution sources from the WHO.

In developing economies, indoor pollution affects 3 billion people who are exposed to smoke from the burning of coal, biomass, and animal dung for cooking, heating, and lighting.

3B

people in developing economies are exposed to indoor smoke from coal, biomass and animal dung

Air pollution and mortality

Leading causes of death worldwide, in rank order
1 High blood pressure
2 Dietary risks
3 Smoking
4 Air pollution
3.7M outdoor air pollution deaths, WHO estimate
4.3M indoor air pollution deaths, WHO estimate
4.5M projected outdoor deaths per year, IEA

One in eight deaths worldwide is linked to pollution in the air. These contaminants cause a wide range of illnesses, including lung and heart diseases, as well as stroke and cancer. WHO estimates outdoor air pollution deaths to be 3.7 million and indoor air pollution deaths to be 4.3 million. This places air pollution as the fourth leading cause of death, following high blood pressure, dietary risks and smoking.

The IEA projects outdoor air pollution-related deaths could rise to 4.5 million per year due to massive growth in fossil-fuel use and desertification in Asia.

$225B

annual lost productivity, World Bank estimate

$5T

order of total cost once welfare is factored in

In addition to mortality, the economic cost of air pollution is staggering. Lost labor due to sick days, medical bills, and reduced agricultural output are among the damages. The World Bank estimates annual lost productivity to be at least $225 billion. When welfare costs are factored in, the costs balloon to an order of $5 trillion.

Where does pollution come from?

Industrialization, urbanization, desertification and the burning of fossil fuel have long-term consequences on air quality. There is no doubt human activity has an impact on air pollution. Globally, between 1979 and 2013, the global burnable area of long fire weather seasons has doubled due to drought. Most recently in China, deforestation has led to severe dust storms.

Map of a May 2017 dust storm across northern China with the Three-North Shelterbelt outlined, and a chart of hourly PM2.5 in Beijing peaking at 684 micrograms per cubic metre
A May 2017 dust storm enveloped northern China, pushing hourly PM2.5 in Beijing to 684 μg/m3. Graphic: Reuters (W. Foo, J. Wu).

What about ozone?

6 to 30 miles up

Shields the planet

Ozone in the upper atmosphere blocks harmful UV rays.

At ground level

Toxic to humans and animals

Forms when ambient VOCs react with nitrogen oxides under sunlight. More likely when the weather is warm and sunny.

In addition to indoor emissions of VOCs, vehicles and power plants emit VOCs when fuel is not completely burned. They are also emitted from industrial sources that use chemical solvents and paints.

Ozone, a colorless gas, forms when ambient VOCs react with nitrogen oxides under sunlight. While ozone in the upper reaches of the atmosphere (6 to 30 miles above ground level) shields the planet from harmful UV rays, ozone at ground level is toxic to humans and animals. Ozone pollution is more likely to form when the weather is warm and sunny.

Ozone levels in western U.S. states continue to increase despite a 50% reduction in domestic emissions since 1990. This is due to pollutants that migrate thousands of miles from China, India, and other Asian countries, which are the fastest growing emitters in the world. Air pollution is not only a domestic issue. It is a transboundary problem that all countries face, regardless of their own emissions.

Is air pollution increasing in the US?

99%

fall in airborne lead — the most dramatic reduction of the six criteria pollutants

In spite of population growth and growing fossil fuel use in the US, the average national concentration of all six criteria pollutants fell between 1990 and 2010 by enforcing compliance to the NAAQS. The most dramatic reduction in air pollution is lead, which fell 99%. Nevertheless, ozone and PM remain problematic health hazards.

Line chart of US national air quality concentration averages from 1990 to 2015, showing every criteria pollutant trending downward relative to the national standard, with lead falling fastest
National air quality concentration averages, 1990–2015, shown as the percentage above or below the most recent national standard.

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